5.1 What is a Chemical Bond When two atoms of same or different elements approach each other, the energy of the combination of the atoms becomes less than the sum of the energies of the two separate atoms at a large distance. We say that the two atoms have combined or a bond is formed between the two. The bond is called a chemical bond. Examples and characteristics of 5 types of bonds Increase in bonding energy over similar molecules without hydrogen bonds Hydrogen H 2 O, HF 0.25-0.6 Ne, Ar,Kr, Xe, 0.05-0.2 Low melting and boiling points CHCl 3 Fluctuating or permanent dipole Nondirected bond, structures of very high coordination and density; high electrical conductivity.

Chemistry 253

Chemical Bonds In Solids Chemical Bonds In Solids by Jeremy K. Download it Chemical Bonding In Solids books also available in PDF, EPUB, and Mobi Format for read it on your Kindle device, PC, phones or tablets. This book will be ideal for students taking courses in solid state chemistry, materials chemistry, and solid state physics. CHEMICAL BONDING CONTENTS 2 Electronegativity 3 Road Map 4 Types Of Bonding 5 Properties Controlled By Chemical Bond 6 Polar Bonds 7 Metallic Bonding 8 Intermolecular Forces 9 Ions: Counting Electrons And Protons 10 Ionic And Atomic Radii 11 Ions And Energy 12 Lithium Fluoride 13 Crystal Packing 14 Crystal Packing 15 Crystal Packing 16 Covalent. This book offers a clear, pedagogical synthesis of chemical bonding theory and structural considerations in solid state chemistry at the level of a first year graduate course. It will also be of interest to a large variety of researchers interested in applying the latest theoretical ideas to their more applied efforts in synthesizing and characterizing important new materials.

MaterialsChemistry

Spring 2016

Instructor:

Professor Peidong Yang,

239 Hild.,Tel: 643-1545

Email: p_yang@berkeley.edu

Office Hours:Friday10-12pm, 239 Hild.

Teaching Assistant

Nick Kornienko
nick.kornienko.berkeley@gmail.com

Description:

This course is intendedprimarily as an introduction course to materials and solid state chemistry forgraduate students and advanced undergraduate students. The objective is tounderstand solids from a chemical perspective and introduce general solid statesynthesis methodologies and characterization techniques. Topics covered willinclude: structure and structure determination of crystalline solids; freeelectron model for metals; electronic band structure; chemical bonding insolids; structure-property relationships.

Grading:

Problem sets (2)40%

Final60%

Main Reference Books: (Reservedat Chem./Phys./Engineering Lib.)

West: Solid State Chemistry and its Applications (Wiley,1988)

West: Basic solid state chemistry (Wiley, 1999).

Gersten and Smith: The Physics andChemistry of Materials (Wiley, 2001)

Hoffmann: Solids and Surfaces (VCH, 1988)

Burdett: Chemical Bonding in Solids (Oxford 1995)

Ashcroft and Mermin: Solid StatePhysics (Saunders College, latest edition)

Kittel: Introduction to solid State Physics (Wiley, 1996)

William D. Callister Jr. Materials Science and Engineering,an Introduction (Wiley)

Cheetham and Day: Solid StateChemistry: Techniques (Oxford, 1987)

Cheetham and Day: Solid StateChemistry: Compounds (Oxford, 1992)

Cox: The Electronic Structure and Chemistry of Solids(Oxford, 1987)

Wells: Structural Inorganic Chemistry (Clarendon Press,1984)

Wold and Dwight: Solid StateChemistry (Chapman Hall, 1993)

Courtesy ofDr. S. Heyes,Univ. Oxford, for crystal structural models in the Lectures.

Hereis a tentative list of the lecture topics.

DateTopicSuggestedReadings

Materials Chemistry I

Materials Chemistry II

Chemical Bonding In Solids Burdett Pdf Printable

Materials Chemistry III

Format

Häftad (Paperback)

Språk

Engelska

Antal sidor

336

Utgivningsdatum

1995-05-01

Upplaga

illustrated ed

Förlag

OUP USA

Illustrationer

figs.tabs. bibliog.

Dimensioner

233 x 162 x 21 mm

Vikt

558 g

Antal komponenter

1

ISBN

9780195089929

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1: Molecules 1.1: The H2 Molecule: Molecular Orbitial Approach 1.2: The H2 Molecule: Localized Approach 1.3: Energy Levels of HHe 1.4: Energy Levels of Linear Conjugated Molecules 1.5: Energy Levels of Cyclic Polyenes 1.6: Energy Differences and Moments 1.7: The Jahn-Teller Effects 2: From Molecules to Solids 2.1: The Solid as a Giant Molecule 2.2: Some Properties of Solids from the Band Picture 2.3: Two Atom Cells 2.4: The Peierls Distortion 2.5: Other One-Dimensional Systems 2.6: Second Order Peierls Distortions 3: More Details Concerning Energy Bands 3.1: The Brillouin Zone 3.2: The Fermi Surface 3.3: Symmetry Considerations 4: The Electronic Structure of Solids 4.1: Oxides with the NaCl, TiO2 and MoO2 Structures 4.2: The Diamond and Zincblende Structures 4.3: 'Localization' of 'Delocalized' Orbitals in Solids 4.4: The Structure of NbO 4.5: Chemical Bonding in Ionic Compounds 4.6: The Transition Metals 4.7: The Free-Electron Model 4.8: Compounds between Transition Metals and Main Group Elements 4.9: The Nickel Arsenide and Related Structures 4.10: Molecular Metals 4.11: Division into Electronic Types 5: Metals and Insulators 5.1: The Importance of Structure and Composition 5.2: The Structures of Calcium and Zinc 5.3: Geometrical Instabilities 5.4: Importance of Electron-Electron Interactions 5.5: Transition Metal and Rare Earth Oxides 5.6: Effect of Doping 5.7: Superconductivity in the C60 Series 5.8: High-Temperature Superconductors 6: The Structures of Solids and Pauling's Rules 6.1: General Description of Ion Packings 6.2: The First Rule 6.3: The Second Rule 6.4: The Third Rule 6.5: The Fifth Rule 6.6: The Description of Solids in Terms of Pair Potentials 6.7: More About the Orbital Description of Silicates 7: The Structures of Some Covalent Solids 7.1: Electron Counting 7.2: Change of Structure with Electron Count 7.3: Structures of Soem AX2 Solids 7.4: Structures Derived from Simple Cubic or Rocksalt 7.5: The Stability of the Rocksalt and Zincblende Structures 7.6: The Structures of the Spinels 7.7: Distortions of the Cadmium Halide Structure: Jahn-Teller Considerations 7.8: Distortions of the Cadmium Halide Structure: Trigonal Prismatic Coordination 7.9: Distortions of the Cadmium Halide Structure: t2g Block Instabilities 7.10: The Rutile Versus Cadmium Halide Versus Pyrite Structures 7.11: Second Order Structural Changes 8: More About Structures 8.1: The Structures of the Elements 8.2: The Structures of Some Main Group Intermetallic Compounds 8.3: The Hume-Rothery Rules 8.4: Pseudopotential Theory 8.5: The Structures of the First Row Elements 8.6: The Coloring Problem 8.7: Structural Stability and Band Gap